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Topic: Lower than expected boiling point?  (Read 5699 times)

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Offline FAN7OM

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Lower than expected boiling point?
« on: October 09, 2016, 01:38:03 PM »
In my lab we performed a distillation and my mixture boiled at 50 degrees celsius. The lab mentioned that the unknown organic solvent (either acetone or isopropanol) is mixed with salt water. Using gas chromatography, my retention time matched that of acetones retention time.

This is frustrating because the chromatography points towards acetone being the unknown, however the lowered boiling point of the mixture contradicts this (acetone boils at 56).

Any ideas would be greatly appreciated.

Offline AWK

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Re: Lower than expected boiling point?
« Reply #1 on: October 09, 2016, 04:20:34 PM »
Incorrect mounting of thermometer.
AWK

Offline FAN7OM

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Re: Lower than expected boiling point?
« Reply #2 on: October 09, 2016, 04:29:43 PM »
lol I actually did not think of that, it sounds about right though.

Thanks!

Offline Enthalpy

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Re: Lower than expected boiling point?
« Reply #3 on: October 13, 2016, 05:11:23 PM »
The odour should tell, unless something else stings more.

Offline Babcock_Hall

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Re: Lower than expected boiling point?
« Reply #4 on: October 13, 2016, 06:07:04 PM »
Do you have a drawing of the apparatus?  Students often place the thermometer incorrectly, in my experience.

Offline jasongnome

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Re: Lower than expected boiling point?
« Reply #5 on: October 14, 2016, 01:52:44 AM »
I think AWK and Babcock Hall have hit the nail on the head.

The thermometer should be positioned at the junction of the condenser.
When you are courting a nice girl, an hour seems like a second. When you sit on a red-hot cinder a second seems like an hour. That's relativity. (Albert Einstein)

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