C-O stretching generally occurs at 1320 - 1210 cm-1, at a medium intensity. Then which one here can be for C-O single bond? 1395 and 1432 cm-1 can they be assigned for C-O? because they are of medium intensity. 1265 is high, 1342 is low in intensity, so I think they are not for C-O.
Then the preoblem is how to know the position of Br in the chain. Is it at the terminal C or at the alpha C? I cannot understand this.