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Topic: Gas Phase Ozonolysis Mechanism prediction  (Read 1804 times)

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Offline Ch-Eng

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Gas Phase Ozonolysis Mechanism prediction
« on: May 24, 2017, 06:57:57 AM »
Hi,

Can anyone help me with the following:
I could like to write the mechanism of gas phase ozonolysis of VOCs.
e.g. alpha-terpinene + O3 = tetrahydrofura-2-none 3,[2 pentynyl] 4- methyl ? and/or 2,3 octanedione

I only have basic knowledge of organic chemistry and reading about ozonolysis from books did not help me. Please suggest the steps I should follow to be able to write the mechanism of VOCs ozonolysis as I have other compounds to do as well: ocimene, a-farnesene, linalool and myrcene.

Many thanks

Offline wildfyr

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Re: Gas Phase Ozonolysis Mechanism prediction
« Reply #1 on: May 24, 2017, 03:59:41 PM »
Well, wikipedia has the mechanism right in the "ozonolysis" article. https://en.wikipedia.org/wiki/Ozonolysis#Reaction_mechanism. All your compounds are pretty much multi-alkenes, and ozonolysis will occur indiscriminately at each one. If you aren't able to follow the mechanism in that article, then there is quite a bit of organic chemistry which we can't really teach you over the internet. Perhaps this Khan academy video will help https://www.youtube.com/watch?v=bFj3HpdC4Uk

Offline Ch-Eng

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Re: Gas Phase Ozonolysis Mechanism prediction
« Reply #2 on: May 25, 2017, 10:41:16 AM »

Thank you very much for replying :) .

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