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Topic: IUPAC naming this molecule? (unexpected name)  (Read 2032 times)

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Offline Traumatic Acid

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IUPAC naming this molecule? (unexpected name)
« on: September 08, 2018, 12:45:24 AM »
Hi there.
Recently In class I was given a molecule to name:

HOCH2CH(CH2CH3)CH(NH2)CH3


 I have attached an image of the drawing if it helps.
After the tutor said it was called "3-Amino-2-ethyl-1-butanol"
I'm confused as to why he didn't identify the longest carbon chain?
I'm probably wrong, but wouldn't this molecule be called something allong the lines of: 2-Amino-3-Hydroxymethyl Pentane?
I'm guessing there are some situations where you ignore the longest chain and treat part of it as a substituent?
Someone please explain  ;D
Thanks

Offline kriggy

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Re: IUPAC naming this molecule? (unexpected name)
« Reply #1 on: September 08, 2018, 04:43:16 AM »
Well, my nomenclature is rusty since I started using chemdraw to name my stuff but IIRC, you are looking for the longest chain with the highest priority group which in this case is butanol and then you add substituents

Offline Traumatic Acid

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Re: IUPAC naming this molecule? (unexpected name)
« Reply #2 on: September 08, 2018, 10:20:54 PM »
Okay, kinda makes sense. Another thing I need to watch out for  ;D

Cheers

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