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Topic: Chemical kinetics  (Read 1146 times)

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Offline INeedSerotonin

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Chemical kinetics
« on: October 30, 2019, 10:32:25 PM »
The reaction between persulfate and iodide, at 25°C, is given as

S2O8-- + 3 I- --> 2 SO4-- + I3-

and it shows a velocity, determined experimentally, as

v = k. [S2O8--] . [i-]

Assign "true" or "false" to the following propositions:

I) This is an oxirreduction reaction;
II) This is a second-order reaction;
III) the reaction rate is directly proportional to the concentration of the reagents;
IV) the rate of disappearance of  [S2O8--] is three times greater than the rate of disappearance of I-

Which one of these are correct?

Answer: I, II, and III

I don't understand. How come (IV) is not true? Isn't the rate of disappearance inversely proportional to the coefficients?

Offline AWK

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Re: Chemical kinetics
« Reply #1 on: October 31, 2019, 03:32:03 AM »
Maybe the inverted statement is correct.
AWK

Offline mjc123

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Re: Chemical kinetics
« Reply #2 on: October 31, 2019, 05:25:04 AM »
What do you think the coefficients mean? 3 I- are consumed for every S2O82-.

You may be getting confused with
rate of reaction = 1/a*d[A]/dt
but that is because
d[A]/dt = a* reaction rate

Offline INeedSerotonin

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Re: Chemical kinetics
« Reply #3 on: October 31, 2019, 09:02:32 AM »
Thank you both for helping me. I was indeed getting confused by the algebra.

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