the key word here is "yield"
by definition,
theoretical yield = maximum amount possible if the reaction goes to completion
actual yield = amount recovered
% yield = (actual yield / theoretical yield) * 100%
or if it helps, the % yield is a measure of the efficiency of your overall reaction, collection, purification processes.
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you were given this information
530mg of solid (recovered)... this is "actual yield"
63% yield
so
theoretical yield = 530 / 0.630 = 841mg
meaning
IF the reaction went to completion and IF you isolated and purified the solid S2
THEN you could have recovered 841mg of S2
but you didn't. You only recovered 530mg of S2... whatever that is.
so your overall "efficiency" was (530 / 841) * 100% = 63%