I am trying to add a methyl group to an arene. But I find only three synthesis-protocolls:
Wurtz-fittig: from bromoarene derivate with CH3I and Na
Friedel-Craft: directly on the ring with CH3Cl and FeCl3/AlCl3
Methylation by Birch-reduction: MTM-Cl and ZnCl followed by raney-nickel
Other hits on scifinder involved photolysis reactions.
Did I miss anything?
Thank you for all suggestions...