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Imagine dissolving 1 mole of Na3PO4. How many moles of Na+ will be present in the solution?
You know for every moles of Na3PO4 . H2O you get 3 moles of Na+, correct?Now, all you have to do is find how many moles of Na+ you want. Can you do that? You then know for every 3 moles of Na+ you want, you need 1 mol of Na3PO4.H2O.