Detailed answer:-
First, calculate the 'effective' moles of solute by calculating actual moles and then multiplying by the number of
'particles' per mole (here we use the symbol 'DF'-dissolving factor for that term).
moles(solute)=DF*mass(solute)/grams formula weight(solute) [itex]\Rightarrow[/itex]2*17.64/56.00=0.6302
Then, after determining the number of kg of solvent, calculate the molality.
kg(H2O)=grams(H2O)/1000 [itex]\Rightarrow[/itex]458.1/1000=0.4581
m=moles(solute)/kg(H2O) [itex]\Rightarrow[/itex]0.6302/0.4581=1.376
The boiling point elevation and freezing point depression are determined by multiplying the molality by the appropriate constants.
ΔT
b=K
b*m [itex]\Rightarrow[/itex] 0.5120*1.376=0.7044
ΔT
f=K
f*m [itex]\Rightarrow[/itex]1.860*1.376=-2.559
Finally, the resultant boiling and freezing points for the solution are calculated using the 'normal' values.
T
b= 100 + ΔT
b 100 +0.7044=100.70
T
f= 0.00 -ΔT
f 0.00 -2.559 =-2.559