January 02, 2025, 02:43:47 PM
Forum Rules: Read This Before Posting


Topic: Freezing point and boiling point of aqueous solution  (Read 2658 times)

0 Members and 1 Guest are viewing this topic.

Offline Win,odd Dhamnekar

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +0/-5
  • Gender: Male
  • Stock Exchange Trader, Investor,Chemistry Hobbyist
Freezing point and boiling point of aqueous solution
« on: April 22, 2021, 05:12:54 AM »
If Potassium Hydroxide (KOH) weighing 17.64 g was dissolved in 458.1 g water, what is the freezing point and boiing point of the solution?

My answer: Boiling point of the solution is 100.7°C and freezing point of the solution is -2.559°C.

Is this answer correct?   
« Last Edit: April 22, 2021, 06:35:29 AM by Win,odd Dhamnekar »
Any science consists of the following process.
 1) See 2) Hear 3) Smell if needed 4) Taste if needed
5) Think 6) Understand 7) Inference 8) take decision [Believe or disbelieve, useful or useless, healthy or unhealthy, cause or effect, favorable or unfavorable, practical or theoretical, practically possible or practically impossible, true or false or  any other required criteria]

Offline Orcio_87

  • Full Member
  • ****
  • Posts: 440
  • Mole Snacks: +39/-3
Re: Freezing point and boiling point of aqueous solution
« Reply #1 on: April 22, 2021, 05:29:21 AM »
Quote
My answer: freezing point of the solution is 100.7°C and boiling point of the solution is -2.559°C.

Is this answer correct?   
It's wrong as boiling point should be higher than melting point.

But those values are wrong anyway.
« Last Edit: April 22, 2021, 05:52:05 AM by Orcio_Dojek »

Offline Win,odd Dhamnekar

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +0/-5
  • Gender: Male
  • Stock Exchange Trader, Investor,Chemistry Hobbyist
Re: Freezing point and boiling point of aqueous solution
« Reply #2 on: April 22, 2021, 06:39:04 AM »
Sorry, I made mistake in typing the answer. Now i have corrected my answer. You may check it now.
Any science consists of the following process.
 1) See 2) Hear 3) Smell if needed 4) Taste if needed
5) Think 6) Understand 7) Inference 8) take decision [Believe or disbelieve, useful or useless, healthy or unhealthy, cause or effect, favorable or unfavorable, practical or theoretical, practically possible or practically impossible, true or false or  any other required criteria]

Offline Orcio_87

  • Full Member
  • ****
  • Posts: 440
  • Mole Snacks: +39/-3
Re: Freezing point and boiling point of aqueous solution
« Reply #3 on: April 22, 2021, 07:01:27 AM »
These values are wrong anyway, it is like changes of temperature were twiced.

Offline Win,odd Dhamnekar

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +0/-5
  • Gender: Male
  • Stock Exchange Trader, Investor,Chemistry Hobbyist
Re: Freezing point and boiling point of aqueous solution
« Reply #4 on: April 22, 2021, 07:52:36 AM »
Detailed answer:-

First, calculate the 'effective' moles of solute by calculating actual moles and then multiplying by the number of
 'particles' per mole (here we use the symbol 'DF'-dissolving factor for that term).

moles(solute)=DF*mass(solute)/grams formula weight(solute) [itex]\Rightarrow[/itex]2*17.64/56.00=0.6302

Then, after determining the number of kg of solvent, calculate the molality.

kg(H2O)=grams(H2O)/1000 [itex]\Rightarrow[/itex]458.1/1000=0.4581

m=moles(solute)/kg(H2O) [itex]\Rightarrow[/itex]0.6302/0.4581=1.376

The boiling point elevation and freezing point depression are determined by multiplying the molality by the appropriate constants.

ΔTb=Kb*m [itex]\Rightarrow[/itex] 0.5120*1.376=0.7044
ΔTf=Kf*m [itex]\Rightarrow[/itex]1.860*1.376=-2.559

Finally, the resultant boiling and freezing points for the solution are calculated using the 'normal' values.

Tb= 100 + ΔTb :rarrow: 100 +0.7044=100.70

Tf= 0.00 -ΔTf :rarrow: 0.00 -2.559 =-2.559
« Last Edit: April 22, 2021, 09:03:10 AM by Win,odd Dhamnekar »
Any science consists of the following process.
 1) See 2) Hear 3) Smell if needed 4) Taste if needed
5) Think 6) Understand 7) Inference 8) take decision [Believe or disbelieve, useful or useless, healthy or unhealthy, cause or effect, favorable or unfavorable, practical or theoretical, practically possible or practically impossible, true or false or  any other required criteria]

Offline Orcio_87

  • Full Member
  • ****
  • Posts: 440
  • Mole Snacks: +39/-3
Re: Freezing point and boiling point of aqueous solution
« Reply #5 on: April 22, 2021, 09:18:27 AM »
Right, values should be twiced due to dissociation (KCl -> K+ + Cl-).

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27891
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Freezing point and boiling point of aqueous solution
« Reply #6 on: April 22, 2021, 02:01:34 PM »
First, calculate the 'effective' moles of solute by calculating actual moles and then multiplying by the number of
 'particles' per mole (here we use the symbol 'DF'-dissolving factor for that term).

No need to reinvent the wheel: https://en.wikipedia.org/wiki/Van_%27t_Hoff_factor
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Sponsored Links