November 21, 2024, 07:47:12 AM
Forum Rules: Read This Before Posting


Topic: How to determine the strength of a metal-ligand interaction?  (Read 2339 times)

0 Members and 1 Guest are viewing this topic.

Offline sakuralovebot

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
How to determine the strength of a metal-ligand interaction?
« on: November 18, 2022, 07:02:12 PM »
Currently having to judge between the strength of two metal-ligand interactions:
Co3+ --- OH– and Co2+ --- SH–. I know that metals with a higher positive charge make better Lewis acids, so I feel like it might be the OH complex. However, OH- is a stronger lewis base than SH- is, and strong acids interact better with weaker bases, right?

Google + textbook is not helping. Any advice would be appreciated.

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27852
  • Mole Snacks: +1813/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: How to determine the strength of a metal-ligand interaction?
« Reply #1 on: November 19, 2022, 05:10:46 AM »
Broadly speaking the only sure way is to compare complex stability constants. While crystal field theory and/or ligand field theory give some hints in the end you always need experimental confirmation.

In some cases CFT and LFT give more or less unambiguous answers, no idea if that's one of them, haven't used them for way too long :(
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Sponsored Links