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Topic: Why si this possible? FeSO4 + (COOH)2 = H2SO4 + Fe2(C2O4)3  (Read 1005 times)

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Offline hartalinstalin69

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Why si this possible? FeSO4 + (COOH)2 = H2SO4 + Fe2(C2O4)3
« on: December 28, 2023, 07:21:39 PM »
So, I have been trying to understand this reaction recently: (COOH)2 + FeSO4 → Fe(COO)2 + H2SO4
The thing I don't understand is that oxalic acid is a weak acid compared to sulphuric acid which is a strong acid.
Shouldn't it stay as it is due to this? My knowledge tells me that this reaction could happen only this way:
 Fe(COO)2 + H2SO4 :rarrow: (COOH)2 + FeSO4

Idk, please no hate and thanks for the answers  :)

Offline Borek

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Re: Why si this possible? FeSO4 + (COOH)2 = H2SO4 + Fe2(C2O4)3
« Reply #1 on: December 29, 2023, 03:09:26 AM »
Yes, I am not convinced reaction as written will proceed to the end. Where did you got it from?

This will be an equilibrium system. Solubility of dihydrate listed as 0.097 g per 100 mL of water suggests Ksp around 3×10-5, without calculating exact numbers: if you just mix sulfate with oxalic acid I would expect some precipitate, but definitely not all iron will react.

Also: oxalate is a strong complexing agent, reaction equation can refer to the creation of a soluble complex.
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