Chlorine is diatomic if it's by itself. Aluminum plus Chlorine would yield this:
2 Al + 3 Cl2 = 2 AlCl3
so it would yield this:
2 Al
AL is not diatomic
3 Cl2
Chlorine is diatomic
2 AlCl3
Aluminum has a charge of +3 and Chlorine has a charge of -1 so you need 3 Chlorine so balance it out which means AlCl3
remember HONClBrIF, it sounds like huncklebriff so it's easy to remember.
Hydrogen, Oxygen, Nitrogen, Chlorine, Bromine, Iodine, and Fluorine are all diatomic.