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Topic: Boiling Point of Organic Mixture  (Read 3687 times)

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Offline Sis290025

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Boiling Point of Organic Mixture
« on: December 06, 2006, 08:52:08 AM »
If one has a mixture of borneol (standard bp: 210 C) and verbenone (standard bp: 227.5 C), would the mixture's boiling point theoretically be the average of the two (218.75 C), or is there something else I have to take into consideration (vapor pressure)?

Thanks for any help.

Offline mir

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Re: Boiling Point of Organic Mixture
« Reply #1 on: December 06, 2006, 04:31:35 PM »
Quote
or is there something else I have to take into consideration (vapor pressure)?
Are the liquids miscible?
Do they form an azeotrope?
No single thing abides, but all things flow.
Fragment to fragment clings, and thus they grow
Until we know and name them.
Then by degrees they change and are no more
The things we know.
- Titus Lucretius Carus

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Offline Custos

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Re: Boiling Point of Organic Mixture
« Reply #2 on: December 06, 2006, 07:26:11 PM »
A mixture of two miscible liquids should start to boil at (or very near) the boiling point of the lowest boiling liquid. That's the essence of separation by distillation.

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