General rule for addition and subtraction to keep the right amount of certainty in our results is to record your result in the same number of decimal places as the number with the fewest decimal places.
For example,
.001 + .00003 = .001
But this is a convenient way of skipping the more important aspects of analytical chemistry, as we are ignoring our reliability here.
Generally speaking, this should be enough for your case.
When you have multiple operations, such as multiplication followed by say addition, you follow operation rules and determine significance in that order.
For example,
2.34 x 3.423 + 2.000 = 10.00
Your multiplication should only carry 3 digits, of course. Being careful not to round off and carry at least 2 more digits than 3, for example 8.0098 instead of 8.01, add this to 2.000 keeping in mind that your previous calculation had 3 digits, with
2 decimal places.
After you have multiplied your 3 significant digits does not mean that after adding to 2.000 you have an answer with 3 significant digits. Because now you are adding, the rule is to record the number with the fewer number of decimal places, which is 2.
If you rounded through, it would be easier to see, but I warn you not to round until the very end and carry some extra digits throughout. This is just for clarification:
Rounding through2.34 x 3.423 = 8.01 (
3 sig figs)
8.
01 + 2.000 = 10.01 (
2 decimal places)
Notice that the final answer is 10.01 because we rounded in the middle of our calculation.
Do not do this. Only round at the very end. This, as calculated above, should give you
10.00. You have to carry a couple of extra digits (2 or 3 should be enough) and keep in mind how many significant ones you need throughout the calculation.
Essentially, I have restated in a different way what Borek has said. Whichever way is easier for you to understand.