September 21, 2024, 01:39:44 AM
Forum Rules: Read This Before Posting


Topic: Problem involving Kp  (Read 3059 times)

0 Members and 1 Guest are viewing this topic.

Offline lucasloredo

  • New Member
  • **
  • Posts: 8
  • Mole Snacks: +0/-0
Problem involving Kp
« on: February 17, 2007, 08:15:59 PM »
I'm not sure even where to start on this problem:

given the equation     2NaHCO3 (s) <--------->  Na2CO3 (s) + H2O (g) + CO2 (g)

A sample of 100. grams of solid NaHCO3 was placed in a previously evacuated rigid 5.00 liter container and heated to 160 degrees C. Some of the original solid remained and the total pressure in the container was 7.76 atmospheres when equilibrium was reached. Calculate the number of moles of H20 (g) present at equilibrium.

I tried using Kp and partial pressures but I haven't done enough of these kind of problems to know what to do. Thanks in advance!

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27790
  • Mole Snacks: +1807/-411
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Problem involving Kp
« Reply #1 on: February 18, 2007, 05:25:43 AM »
Gas produced is an equimolar mixture of CO2 and H2O - so H2O is exactly half of it.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline lucasloredo

  • New Member
  • **
  • Posts: 8
  • Mole Snacks: +0/-0
Re: Problem involving Kp
« Reply #2 on: February 18, 2007, 10:38:21 AM »
yes that is what I was thinking, which would make the pressure of the H2O gas at 3.75 atm.

Ah, now I understand, so after finding its pressure you use the formula PV = nRT to find the moles . . . gotcha :)

Thanks!

Sponsored Links