Also interesting is the Sabatier reaction where carbon dioxide is catalytically activated in the presence of hydrogen, which fully
hydrogenates the adsorbed carbon species to methane, with accompanying water formation:
CO2 + 4H2 ? CH4 + 2H2O
This reaction is moderately exothermic, H° = -165-kJ/mol.
The stoichiometric reverse water-gas shift reaction, which typically operates close to equilibrium, is mildly
endothermic, ?H° = 41.2-kJ/mol:
CO2 + H2 ? CO + H2O (2)
This process is commonly used to tailor the hydrogen concentration of mixed syngas streams in industrial operations. Due to its reversibility, however, maximum conversions and selectivities are typically governed by equilibrium. Typical water-gas shift catalysts are used but at higher temperatures.
And yes CO2 may react with some Me-oxides (i am not sure for Fe2O3) at high temperatures when it could passes oxidation properties.