Ooh, ofcourse, I feel abit dumb now.
I'm quite new to the topic and I was getting abit 'led astray' by the water in the question, but I got it now;
1) Work out the number of moles of HCl; 0.01dm3 x 1.0M = 0.01 moles HCl, therefore, 0.01 moles H+
pH = -log100.01 = 2
2) Again, work out moles of NaOH (0.02 x 10.M =) 0.02 moles.
pKa = -log100.02 = 1.7
pKa + pKb = 14, so, pKb = 14 - 1.7 = 12.3