The only info you need is the mass percents (which you gave) and the molar mass of CuSO4 and H2O (which you can easily figure out from a periodic table, or look up in a table of physical data).
Consider what the mass percent of H2O means: 32% == 32g H2O per 100g CuSO4*nH2O
Similarly for CuSO4 (anhydrous), 68% == 68g CuSO4 per 100g CuSO4*nH2O
If you convert these masses (32g H2O, 68g CuSO4) to moles then you can figure out the number (n) of moles of H2O present per mole of the hydrate (since there is only one mole of CuSO4 in a mole of the hydrate)