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Topic: Ligand question ! Pi acceptor yes but...  (Read 4436 times)

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Offline faust

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Ligand question ! Pi acceptor yes but...
« on: April 21, 2007, 02:41:56 PM »
Hello!

I'm working in michael addition or Ar-X on MVK by using a cobalt(I) catalyst.

It works good in DMF/Pyridine (9/1) with Co(Bipyridine)2Br2.

But how can you explain the following fact : when I use 2,2'-bisimidazole, only the dimiere Ar-Ar is observed, and no addition on the MVK. Idem with orthophenanthroline!

I know I need a pi acceptor ligand, but I don't understand why the bipyridine is the only ligand that works...

Do you have any suggestion for other ligands?

Thanks a lot

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