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Topic: Buffer pH  (Read 2763 times)

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Offline FouRRaW

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Buffer pH
« on: April 02, 2007, 09:38:47 PM »
Hi, I got a pH buffer solution question i'm a bit confused on....

Acetic acid has a Ka=1.8x10-5. What is the pH of a buffer solution containing 0.15M CH3COOH and 2% CH3COO-?

So mainly i'm not really sure what the 2% means, and what i'm supposed to do with it?

Any tips or advice would be greatly appreciated.

Thanks
-fourraw


Offline AWK

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Re: Buffer pH
« Reply #1 on: April 03, 2007, 01:20:54 AM »
assume 2% w/w and density of solution that of water. Usually percent concentration is used for a specific compound. You need a molecular mass for  a molar concentration calculation
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Offline Borek

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Re: Buffer pH
« Reply #2 on: April 03, 2007, 02:57:14 AM »
You may do as AWK told you, but the question is ambiguous. It may mean 0.15M acetic/acetate total, 2% of acetate, remaining form - acetic acid. In such a case just plug percentages into Henderson-Hasselbalch equation.

What I don't like about this question is that %w/w conversion to molarity will depend on the counterion. 2% w/w CH3COONa solution has different moler concentration than CH3COOCs, and I have never seen w/w concentration given just for ion (CH3COO- in this case).
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