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Topic: Need help on question involving colorless solution/white precipitates  (Read 7858 times)

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Offline xangelofxdeathx

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A colorless solution is known to contain one of these ions. Which ion is present if adding dilute HCl produces a white precipitate that dissolves when the solution is warmed?

A) Ag+
B) Cu2+
C) Hg22+
D) Pb2+

I have no idea how I can figure this problem out  ???

This is what I "think" I am supposed to do:
First, the ion will react with the Cl- in HCl, therefore you get either AgCl, CuCl2, Hg2Cl2, or PbCl2. then I assume I am supposed to know which one is a white precipitate? Oh yeah also CuCl2 is not a precipitate so that one can be eliminated. Hmmm is this the kind of problem where I either know it or don't know it?

Is this the right way to do this problem? Or is there a better way? (The answer is D by the way)

Offline Vixklen

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Re: Need help on question involving colorless solution/white precipitates
« Reply #1 on: April 06, 2007, 01:11:57 AM »
Hg2Cl2 is a yellowish white precipate.
The only white precipitate here is AgCl and PbCl2. From the data I get, AgCl slightly dissolves in 50deg Celcius. While PbCl2 slightly dissolves in 20deg C. That's why a PbCl2 precipitate in a solution could dissolve more than AgCl does when the solution is warmed.

peace
vixklen

Offline AWK

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Re: Need help on question involving colorless solution/white precipitates
« Reply #2 on: April 06, 2007, 01:20:47 AM »
CuCl2 is soluble in water (blue solution).
All other precipitates are colourless (white). Only one of them is soluble in warm water (PbCl2)
AWK

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