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Topic: Plese help me to solve this problem  (Read 7044 times)

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Offline darkangel1

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Plese help me to solve this problem
« on: March 01, 2007, 07:50:36 AM »
Hi,

I have to solve this problem here before next week, but I do not know where I should beginn and how I should solve this problem. I am a biginner concerning physical chemistry. ???

Here is the problem :

On arousal from hibernation, a hamster can raise its body temperature by as much as 30K. Assuming that the heat required for this arises from combustion of fatty acids calculate the weight of fatty acid which would be needed to be oxidised in order to warm up a 100 g hamster.
The delta U for combustion (in the presence of O2 to CO2 and HOH) of solid stearic acid is -11360 kJ/mol - thus you must consider the delta n in order to calculate the corresponding delta H.

The molecular formula of stearic acid is C18H36O2
R = 8.31 J/Kmol
The specific heat of the hamster tissue is 3.30 J/Kg

I would be thankfull if anyone could explain me what to do and how to solve this problem in easy steps.

Thank you in advance!

Offline Borek

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Re: Plese help me to solve this problem
« Reply #1 on: March 01, 2007, 08:14:15 AM »
Do you know what heat balance is?
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Offline darkangel1

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Re: Plese help me to solve this problem
« Reply #2 on: March 01, 2007, 08:44:51 AM »
No, not really. Can you give me an hint?

Offline Borek

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Re: Plese help me to solve this problem
« Reply #3 on: March 01, 2007, 09:00:09 AM »
heat lost = heat gained

Your hamster need to gain enough heat to get warm. First you must calculate how much heat it needs using methods used for heat balance calculations. Google.
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Offline darkangel1

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Re: Plese help me to solve this problem
« Reply #4 on: March 01, 2007, 12:26:49 PM »
Hi, I googled, but only found progams that calculate. Next week I must explain it in front of the blackboard. I mean I still did not figure out how it goes. The professor gaves us the hint to consider deltaG = deltaH - TdeltaS.

Physical chemistry is a complete new topic for me and it would be great if someone could explain me the solution to this problem.

Offline Donaldson Tan

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Re: Plese help me to solve this problem
« Reply #5 on: March 06, 2007, 07:48:45 AM »
What is the amount of heat (Q) needed to raise the body temperature of a 100g (m) hamster by 30K (dT) since you already know its heat capacity (Cp)? Hint: Q = m.Cp.dT

How much fat (mfat) do you need to generate that amount of heat (Q)?
"Say you're in a [chemical] plant and there's a snake on the floor. What are you going to do? Call a consultant? Get a meeting together to talk about which color is the snake? Employees should do one thing: walk over there and you step on the friggin� snake." - Jean-Pierre Garnier, CEO of Glaxosmithkline, June 2006

Offline ua_sinan

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Re: Plese help me to solve this problem
« Reply #6 on: April 12, 2007, 07:41:01 AM »
if u help me about this problem i will pray everyday for u :D

the vapor pressure of a liquid in the temperature range 200 K to 260 K was found to fit the equation:   

               ln(p/torr)=18.361 -- 3036.8/(T/K)

calculate the enthalpy of vaporization of the liquid!!!

the answer=25.25 kj/mol

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