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Topic: Equilibrium question  (Read 3974 times)

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Offline djdato

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Equilibrium question
« on: April 17, 2007, 04:46:57 AM »
hey guys...drawing a blank here...

2HI(g) <----> H2(g) + I2(g)

mixture was prepared by placing 4.0 mol of HI in a 2.0 L vessel at 330 C. At Equilibrium 0.44 mol of H2 and 0.44 mol of I2 were present. Calculate the value of the equilibrium constant at this temperature.

Could someone point me in the right direction?
grateful for help...thnx   ;D
« Last Edit: April 17, 2007, 06:22:48 AM by djdato »
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Offline xiankai

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Re: Equilibrium question
« Reply #1 on: April 17, 2007, 08:05:40 AM »
write out the Kc expression for the reaction, then plug in the values.
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Offline Rich2189

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Re: Equilibrium question
« Reply #2 on: April 17, 2007, 12:19:08 PM »
Kc = [H2][I2]
         [HI]2

Also since it is an all gas  equation you can also use Kp Where p is pressure/ partial pressure.

Kp = p(H2) p(I2)
          p(HI)2
Avogadro's Constant = 6.0221415 × 1023 mol-1

Offline Yggdrasil

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Re: Equilibrium question
« Reply #3 on: April 18, 2007, 03:36:06 AM »
mixture was prepared by placing 4.0 mol of HI in a 2.0 L vessel at 330 C. At Equilibrium 0.44 mol of H2 and 0.44 mol of I2 were present.

If 0.44 mol of H2 and 0.44 mol of I2 are present at equilibrium, how much HI would remain unreacted?

Offline djdato

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Re: Equilibrium question
« Reply #4 on: April 18, 2007, 05:04:21 AM »
hey guys. Thanks for the help. I've found the answer to be K = 0.02. Is this right?
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Offline Rich2189

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Re: Equilibrium question
« Reply #5 on: April 18, 2007, 10:25:11 AM »
Yes that's what I got.

4 - (0.44 X2) = 3.12


(0.44x0.44) divided by 3.122

= 0.01988888

= 0.02 to 1 s.f

And as a note there are no units for this particular equilibrium constant.
Avogadro's Constant = 6.0221415 × 1023 mol-1

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