Dear movies,
I would like to answer such Questions in the same manner and efficiency as you do.
IF your postulate holds, Then I believe You are generating quite a few problems for
several scientists of organic/physical-organic Chemistry.
To use a simple Example first:
Mr. Manfred Hesse; Mr. Herbert Meier; and Mr Bernd Zeeh, report in their
Book: “Spectroscopic Methods for organic Chemistry” (5th Edition; 1st Edition: 1979)
in Chapter about N15 NMR chemical Shifts for:
(E)-Azobenzene in CHCl3 of: N1, N2 = +129.0
(Z)-Azobenzene in CHCl3 of: N1, N2 = +146.5
(E)-Azoxybenzene in CHCl3 of: N1 = -57.1 N2 = -46.7
(Z)-Azoxybenzene in CHCl3 of: N1 = -36.0 N2 = -19.8
Maybe you can tell me that I’m wrong in this case, as I all times meant, that (E)/(Z) are
only older/newer Structure-Naming-Conventions for the same as cis-/trans- is standing.
On the other side, I know from several scientists, who report, to have formed
Metal Complexes of the following general Form: (n = 3 or 4)
____ _____
_____ | ____ |
/ | / |
_____/ | ______/ |
/ \ / | / \ |
H – O ___/ \_____/ | O ____/ \_____/ |
\ / | / \ / |
n * \_____/ + Men+ ---> Men+ | \_____/ |
/ | / |
_ / | \ / |
N==N | N==N |
/ | / |
/ | / |
R1 | R1 |
|___ ___| n
(Sorry for my painting. I hope you will see it anyway clear!
The Rings should be identified as of Bencene nature.)
The correct Electron-Balancing is left to you, because it’s a “hard” job to incorporate it into this picture.
Unfortunately I was not very interested in Complex Chemistry at that time when
they have presented their work, so I didn’t caught the Literature Citation for them, and
at the moment I’m missing the search possibility for it, too.
With a “linear” postulate, such could not be thought possible, without involving quite a lot of Energy!
I would like if you can bring these discrepancies to a good end.
Good Luck!
ARGOS++