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Topic: Balancing Redox reactions.  (Read 4997 times)

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Offline thegunners2004

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Balancing Redox reactions.
« on: July 16, 2007, 07:12:52 PM »
Can someone please check my final answer to see if it is correct. If it is not, please provide me with the correct answer.

I was asked to balance this redox reaction.

Cr2O7-2 (aq) + Pb+2 (aq)-------> Cr+3 (aq) +Pb4+ (aq)


My answer is

6Cr2O7-2 (aq) +22H+(aq) + 2e + 3Pb2------------>4Cr3+(aq) + 2H2O + 3Pb4+


Thanks


Offline Yggdrasil

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Re: Balancing Redox reactions.
« Reply #1 on: July 16, 2007, 08:02:33 PM »
Electrons should not be products or reactants in the final redox reaction.  Plus, the number of chromium atoms (among others) is unbalanced.  What are your two half reactions?

Offline thegunners2004

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Re: Balancing Redox reactions.
« Reply #2 on: July 16, 2007, 11:42:28 PM »
my two half reactions are:

Cr2O7 -2 ------>Cr+3

Pb+3-----------> Pb+4



Offline Yggdrasil

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Re: Balancing Redox reactions.
« Reply #3 on: July 17, 2007, 01:45:21 AM »
The first step would be to balance them.  If the reaction takes place in acidic medium, you can add water and H+ to balance out the oxygens.  If the reaction takes place in a basic medium, use water and OH- to balance the oxygens.

Next, multiply the reactions by constant numbers so that the number of electrons produced by the oxidation reaction is equal to the number of electrons used in the reduction reaction.

Finally, add the two reactions together.  The electrons should cancel out so that the final redox reaction does not have electrons as reactants or products.

[edit: fixed a typo]
« Last Edit: July 17, 2007, 01:12:18 PM by Yggdrasil »

Offline thegunners2004

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Re: Balancing Redox reactions.
« Reply #4 on: July 17, 2007, 02:23:11 AM »
Thanks.It helps to know that electrons can't be present in the final equation...

Offline AWK

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Re: Balancing Redox reactions.
« Reply #5 on: July 17, 2007, 05:07:57 AM »
6Cr2O7-2 (aq) +22H+(aq) + 2e + 3Pb2------------>4Cr3+(aq) + 2H2O + 3Pb4+

You have 6x7=42 oxygen atoms on the left and only 2 on the right, and so on. Your equation is bad balanced.
AWK

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