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Topic: why graphite become unusable?  (Read 3427 times)

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Offline pijoe

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why graphite become unusable?
« on: October 23, 2007, 03:59:28 PM »
i've done brine electrolysis experiment and i managed to gain chlorine gas from the experiment. then i used the same graphite electrode to run one more experiment. but the reaction (bubbles produce) was very very slow compared to my first experiment. it seems like the graphite electrode become unusable. why this thing happens? as i know, we can continuously produce chlorine gas  if the brine is circulate and its concentration is maintain. but in may case, i need to change the graphite electrode every time i run the experiment. anybody can help me here?

Offline Bakegaku

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Re: why graphite become unusable?
« Reply #1 on: October 25, 2007, 12:04:37 AM »
Chlorine gas is a very reactive chemical, and given the fact that it's being formed from Cl- and that constant electron transfers would be happening at the electrode, it wouldn't be unreasonable to assume that the process has been corroding it.  Other than that, are there any other potential impurities in the brine solution?  How did you prepare it?
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Offline 03myersd

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Re: why graphite become unusable?
« Reply #2 on: October 27, 2007, 09:14:08 AM »
I'm not sure if this would affect it or not but would it matter if you accidentally switched the electrodes around? So that the positive electrode is now covered in Sodium?

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