November 25, 2024, 10:28:26 AM
Forum Rules: Read This Before Posting


Topic: Potentiometry: How to calculate E* and n from calibration curve?  (Read 4316 times)

0 Members and 1 Guest are viewing this topic.

Offline nexisrocks

  • Regular Member
  • ***
  • Posts: 29
  • Mole Snacks: +0/-0
Hello,

I'm attempting to write up my lab report, and in this experiment we created our own AgCl electrode and used this to measure the voltage of several standards and an unknown.  A graph of the standards - Etest vs log[Cl-] - was produced as the calibration curve.

My question is, how do the values of E* and n relate to this calibration curve?  Is E* just the slope of the curve?  If so, then n is easy to calculate from there.  If not, I'm not sure what it is...

Thanks!

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27862
  • Mole Snacks: +1813/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Potentiometry: How to calculate E* and n from calibration curve?
« Reply #1 on: April 03, 2008, 03:29:27 AM »
Take a look at Nernst equation. You need slope and intercept.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Sponsored Links