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Topic: Several Basic Question  (Read 3024 times)

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Offline gingi85

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Several Basic Question
« on: December 14, 2007, 05:52:11 AM »
1) Why is -SH a stronger nucleophile that -OH?

2) What determines how acidic a hydrogen in a hydrocarbon is? I presume the terminal carbons will have the most acidic hydrogens because of the stabilization of the carboanion. Also, will a carboanion in an allylic postion have the same stability because of resonance as a carbocation?

3) Will halides attached to bridghead positions react in any nuclephilic substituion or elimination reactions? It seems that all posibilites should be impossible, either because of steric hinderance, double-bonding at a bridgehead, or sp2 hybridization at the bridgehead.

4)When bromine and methyl are attached to the same carbon in a cyclohexane, which one will be strive to be equitorial?

Thank you!

Offline Mitch

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Re: Several Basic Question
« Reply #1 on: December 14, 2007, 06:20:40 AM »
1) Because it has a higher quantum number.

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