Here is a starting point:
Calcium carbonate, CaCO3, is found in nature giving hardness and strength to things such as seashells,
rocks, and eggshells. As hard as this substance is, it will react readily with hydrochloric acid to yield
carbon dioxide gas (and two other products). In this experiment students will design an experiment by
reacting eggshells with 3 M HCl to compare the calcium carbonate composition of white (chicken)
eggshells to brown eggshells.
A good quality eggshell will contain, on average, 2.2 grams of calcium in the form of calcium
carbonate. Approximately 94% of a dry eggshell is calcium carbonate and has a typical mass of 5.5
grams,1 although these values can differ depending on sources. Amounts as low as 78% have been
published.
The remaining mass is composed largely of phosphorus and magnesium, and trace
amounts of sodium, potassium, zinc, manganese, iron, and copper. In the case of brown versus white
eggs, a definitive difference in calcium carbonate amounts may be hard to uncover.
However, consider this. The color of the eggs is nothing more than a result of a different breed. The quality, nutritional value, and taste are identical between white and brown eggs, though two notable
differences are size and price. Brown eggs are usually larger and slightly more expensive. The reason
for the price increase is because brown eggs come from larger hens, which need to be fed more food
daily.
With a larger intake of calcium each day, one might expect the produced egg to have a higher
calcium carbonate content. However, since the eggs are larger, it must be kept in mind that the
calcium is spread over a larger surface area during egg formation. A brown eggshell’s increased
tendency to break, when compared to white, is often attributed to this “thinning out” of calcium during
deposition.