initial [S
2] is 0.008M (0.004 mole/0.5L)
At equilibirum, there is 2*10
-11 moles of S - so [ S ] is 4*10
-11M.
If 2*10
-11 moles of S is formed, that means 1*10
-11 moles of S
2 reacted - this is a negligible amount so effectively [S
2] at equilibirum is still 0.008M.
So K
c = (4*10
-11)
2/0.008 = 2*10
-19