Dear
CopperSmurf;
What you name “
Coupling“ should mean “
Resonance”, but you can also observe “
Couplings” inside a NMR-Spectrum.
And all this does not "work" with
л-Electrons, but is (the “Coupling”) influenced from them.
Maybe to get a small overview of NMR you visit: "
NMR Spectroscopy”.
And also: "
Nuclear Magnetic Resonance”.
I hope I have been of help to you.
Good Luck!
ARGOS
++