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Topic: Bond energies  (Read 10506 times)

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Offline hwgw

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Bond energies
« on: February 29, 2008, 06:46:05 PM »
Calculate the bond energy (O-H) for H2O(g) given the bond energies (O=O), 495 kJ/mol, and (H-H), 435 kJ/mol. The deltaHf for H2O(g) is -242 kJ/mol.

H2(g) + 0.5 O2(g) -> H2O(g)

The calculations turned to be

-242 kJ = (H-H) - 2(O-H)

and solve for (O-H). But I don't understand why only the (O=O) bond energy was neglected from the equation, but also not (H-H). Oxygen has its standard state as O2(g), i understand thats why we neglected it, but hydrogen has its standard state as H2(g), so shouldn't it be neglected too?

Thanks a lot in advance!

Offline FeLiXe

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Re: Bond energies
« Reply #1 on: March 02, 2008, 02:37:44 PM »
in my eyes you have to consider both bond energies
you don't have to look at vaporisation energies since everything is already in the gas phase
Math and alcohol don't mix, so... please, don't drink and derive!

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