October 18, 2024, 02:18:01 PM
Forum Rules: Read This Before Posting


Topic: ??  (Read 3630 times)

0 Members and 1 Guest are viewing this topic.

Offline portugal

  • Regular Member
  • ***
  • Posts: 68
  • Mole Snacks: +2/-5
??
« on: March 24, 2008, 05:49:59 AM »
major product of this (3S)-4,4-dimethyl-3-hydroxymethyl-6-(2'-propenyl)cyclohexene with hydrogen gas and platinum. What the hell does that strucuture look like man never seen something like that especially this 2' stuff.

could someone kindly show me what this looks like

Offline Dan

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 4716
  • Mole Snacks: +469/-72
  • Gender: Male
  • Organic Chemist
    • My research
Re: ??
« Reply #1 on: March 24, 2008, 10:11:41 AM »
OK, start by drawing your cyclohexene core and number the carbons 1 to 6 (with the double bond between 1 and 2).

Then add your substituents:

Hydroxymethyl at postition 3 (note the configuration at this position is specified as S)

Two methyl groups at postition 4

A propenyl at postition 6.

Now the propenyl branch is numbered 1' to 3', and the 2'-propenyl indicates that the double bond of the propenyl branch is between 2' and 3'.
My research: Google Scholar and Researchgate

Offline portugal

  • Regular Member
  • ***
  • Posts: 68
  • Mole Snacks: +2/-5
Re: ??
« Reply #2 on: March 24, 2008, 11:27:17 PM »
(1S)-2,2-dimethyl-1-hydroxymethyl-4-propylcyclohexane

therefore this is the major product based on that structure

Offline Dan

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 4716
  • Mole Snacks: +469/-72
  • Gender: Male
  • Organic Chemist
    • My research
Re: ??
« Reply #3 on: March 25, 2008, 02:36:04 AM »
I would have thought so, yes.
My research: Google Scholar and Researchgate

Sponsored Links