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Topic: oxalic acid  (Read 5111 times)

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Offline vhpk

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oxalic acid
« on: April 29, 2008, 03:25:11 AM »
I'm wondering if the aqueous solution of bromine can oxidize oxalic acid, at first, I think it can be because the inductive effect of 2 carboxyl groups, however, I think of HCOOH, its ability with bromine is because there is -CHO group in its molecule and there are no aldehyde groups in the molecule of oxalic acid. Further more, bromine is a weak oxidized-agent, can't be compared with permanganate kali in acidic solution.
I hope you can help me to solve this problem. Any help would be highly appreciated.
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Offline Borek

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Re: oxalic acid
« Reply #1 on: April 29, 2008, 03:45:40 AM »
What is oxalic acid oxidized to?
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Offline vhpk

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Re: oxalic acid
« Reply #2 on: April 29, 2008, 05:19:29 AM »
What is oxalic acid oxidized to?
I don't know, may be it is oxidized by Br2 to produce CO2 and HBr. Of course, I don't know whether it happens, and the main purpose when I asked was whether oxalic acid react with Br2 in water
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Offline vhpk

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Re: oxalic acid
« Reply #3 on: April 29, 2008, 07:53:53 AM »
Plz help
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Offline AWK

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Re: oxalic acid
« Reply #4 on: April 29, 2008, 08:53:43 AM »
H2C2O4 + HOBr = 2CO2 + H3O+ + Br-
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Offline vhpk

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Re: oxalic acid
« Reply #5 on: April 29, 2008, 07:47:37 PM »
H2C2O4 + HOBr = 2CO2 + H3O+ + Br-
Yeah, so you mean, oxalic acid doesn't react with bromine directly but with the product HOBr - the strong oxidized agent.
Thanks so much for help :)
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Offline AWK

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Re: oxalic acid
« Reply #6 on: April 30, 2008, 12:48:13 AM »
H2C2O4 + HOBr = 2CO2 + H3O+ + Br-
Yeah, so you mean, oxalic acid doesn't react with bromine directly but with the product HOBr - the strong oxidized agent.
Thanks so much for help :)
But HOBr id formed from water and bromine in solution
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