I vaguely remember the following method
1. Boil the leaves for a few minutes in water not alcohol
2. Cut the leaves up and crush them in a pestle and mortar
The point of 1 and 2 is to break the cell walls in the leaves and get at the chloroplasts
3. Add alcohol to the pestle and mortar and keep on crushin'
Slowly, slowly a green liquid will come out and this will contain chlorophyll (and some other things) on which you can perform chromatography
The risk of fire from boiling the alcohol over an "open" flame is high , I would suggest, unless very carefully controlled - so I wouldn't recommend it.