Okay, right here you're using the ideal gas law which is PV=nRT. They have given you the CO
2 value as 4200 mg/L. So in one Liter you have 0.095 moles which you have correctly figured out. So right now everything is good. For your pressure, you can rearrange the ideal gas law to P=RT(n/L) which you have already done. So your calculations are fine. What you don't have right there is R. R is a constant value that does not change. It is something that you have to look up. When you look up the value of R, you will find it as R=SomeNumber (Pressure Unit*VolumeUnit)/(TemperatureUnit*mole). So if you want your units to be in atmospheres, you need to find the value of R which is for use with atmospheres.