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Offline H^j

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Calculating percentage yield...
« on: January 14, 2008, 10:21:11 PM »
Hey everyone.  Quick question that has me stumped.  I get really close to the answer, but I'm off by a couple numbers big enough to make a difference.  Here it is:

For the balanced reaction for forming iron from ome of its ores, hermatite:

Fe2O3 (s) + 3CO----> 2Fe(s) + 3CO2(g )

calculate the percentage yield if 1150 kg of hermatite is reduced by 706 kg of carbon monoxide to give 635 kg of iron. Which reactant is limiting?

I absolutely cannot figure this out!!!  Any help would be appreciated.

Thanks!

Offline Alpha-Omega

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Re: Calculating percentage yield...
« Reply #1 on: January 14, 2008, 10:27:51 PM »
HINT:  Species react mole to mole NOT gram to gram...do the conversions...

Offline IITian

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Re: Calculating percentage yield...
« Reply #2 on: January 15, 2008, 11:54:30 AM »
HINT (well...almost the answer!)

Molecular weight of the species involved:

Fe2O3 = 159.69

CO = 28.01

Fe = 55.847

CO2 = 44.01

your balanced rxn shows that 1 mole of Fe2O3 reacts with 3 moles of CO to form 2 moles of Fe and 3 moles of CO2. I guess you can figue it out...

Offline Lilly

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Re: Calculating percentage yield...
« Reply #3 on: October 13, 2008, 07:29:47 PM »
Theoratical / Actual yield
Step 1: Calculate the number of moles of Fe2O3.
Mass/Mr=Moles
1150/159=7.23moles
Maximum amount of Fe2O3 that could be made is 7232.7
Step 2: Calculate the number of moles of Iron produced.
Again Mass/Mr=moles
635/55.9=11.36
Step3: Calculate the percentage yield
7.23/11.36 x 100 = 63%
I think i cracked it..I got practical exam based on this tommorow.
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Offline Borek

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Re: Calculating percentage yield...
« Reply #4 on: October 14, 2008, 02:46:01 AM »
1150/159=7.23moles

OK

Quote
Maximum amount of Fe2O3 that could be made is 7232.7

Doesn't make sense. First, you are not producing Fe2O3, second, no idea what is this number.

Quote
Step 2: Calculate the number of moles of Iron produced.
Again Mass/Mr=moles
635/55.9=11.36

OK

Quote
Step3: Calculate the percentage yield
7.23/11.36 x 100 = 63%

No. First - percentage yield is actual to theoretical, not theoretical to actual, second - theoretical is not 7.23 mole.
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Offline Lilly

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Re: Calculating percentage yield...
« Reply #5 on: October 14, 2008, 10:35:31 AM »
No. First - percentage yield is actual to theoretical, not theoretical to actual, second - theoretical is not 7.23 mole.

I don't know this is the procedure i read in the book. It was actual yield/maximum yield x 100.

How do you suggest it should be done? ..If i am wrong this will help me out. :)
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Offline Borek

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Re: Calculating percentage yield...
« Reply #6 on: October 14, 2008, 01:32:55 PM »
Both procedures - mine and from the book - call for actual yield in nominator. You have put actual yield in denominator. Theoretical and maximal yields are the same in this case, they differ just by name.
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Offline Lilly

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Re: Calculating percentage yield...
« Reply #7 on: October 15, 2008, 03:34:25 PM »
Both procedures - mine and from the book - call for actual yield in nominator. You have put actual yield in denominator. Theoretical and maximal yields are the same in this case, they differ just by name.

OMG such a silly mistake, if i had done that in the practical exam.  :o
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