As I recall, the gasses dinitrogen tetroxide and nitrogen dioxide, exist in equilibrium with one another: N2O4 ⇌ 2NO2 and nitrogen dioxide is brown. My chemistry text book had a sealed glass cylinder of the mix, that went from light brown to dark brown, when put in a warm water bath. Like Borek: says, these gasses are toxic, and I wouldn't let kids play with them. Perhaps someone makes a sphere with liquid crystals on the inner surface, we used to find disks of this sort of substance fascinating, back in the '70's. But we were easily amused, back then.