November 01, 2024, 12:29:27 AM
Forum Rules: Read This Before Posting


« previous next »
Pages: [1]   Go Down

Topic: Barton reduction  (Read 3500 times)

0 Members and 1 Guest are viewing this topic.

Offline Doom91

  • Regular Member
  • ***
  • Posts: 54
  • Mole Snacks: +0/-3
  • Gender: Male
Barton reduction
« on: February 16, 2009, 09:14:54 PM »
Does anyone know the condition and reagent for Barton reduction and why is it used for aliphatic ketone or aldehyde and it is considered milder than Wolff Kishner or Clemmenson reduction
Logged

Offline russellm72

  • Chemist
  • Full Member
  • *
  • Posts: 133
  • Mole Snacks: +10/-7
  • Gender: Male
Re: Barton reduction
« Reply #1 on: February 17, 2009, 05:02:38 AM »
You need to make the S-Xanthate then use AIBN (or similar) as a radical initiator. I have an example in my PhD thesis I think or at least the reference but I'm at work at present.

Do you need to do this reaction experimentally?

R.

Logged

Offline alphahydroxy

  • Full Member
  • ****
  • Posts: 194
  • Mole Snacks: +7/-6
  • I'm a lumberjack, and I'm OK !
Re: Barton reduction
« Reply #2 on: February 17, 2009, 05:18:37 AM »
Seriously, is google broken today or something...?!

Logged

Offline alexjaco

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +1/-0
  • Gender: Male
Re: Barton reduction
« Reply #3 on: February 17, 2009, 12:08:59 PM »
Quote from: alphahydroxy on February 17, 2009, 05:18:37 AM
Seriously, is google broken today or something...?!



Or how about any named reaction organic textbook?!
Logged
Pages: [1]   Go Up
« previous next »
Sponsored Links