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Topic: Potentiometric pH Titrations moles calculation  (Read 5193 times)

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Offline ItalianChick0188

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Potentiometric pH Titrations moles calculation
« on: April 23, 2009, 12:15:09 PM »
So in lab we measured 2 samples of an unknown substance and titrated it  twice with  0.1007 M NaOH using a pH meter model 420A and an Orion pH meter model 310*.

My weight of the unknown for sample 1 was 0.0998 grams. We are asked to calculate the moles of NaOH reacted at the equivalence point.

I made my graphs and found that the equivalence point for Trial 1 was 5.38 mL NaOH with a pH of 8.0.

Would it be 0.0998 g unknown /0.1007 M NaOH?


Offline Borek

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Re: Potentiometric pH Titrations moles calculation
« Reply #1 on: April 23, 2009, 12:51:59 PM »
Reaction equation, please.
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Offline ItalianChick0188

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Re: Potentiometric pH Titrations moles calculation
« Reply #2 on: April 23, 2009, 12:53:22 PM »
HA + NaOH ------ A- + H20 + Na+

Offline ItalianChick0188

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Re: Potentiometric pH Titrations moles calculation
« Reply #3 on: April 23, 2009, 01:05:37 PM »
Wait it would be 0.1007 M NaOH * 0.00538 L = 5.42 X 10 ^ -4 moles NaOH.

Offline ItalianChick0188

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Re: Potentiometric pH Titrations moles calculation
« Reply #4 on: April 23, 2009, 01:26:44 PM »
Alright so I calculated the moles of acid reacted and NaOH which was 5.42 X 10 ^ -4 and I also calculated the MW of the acid and I got 184.13 g/M.

I am now asked to calculate (H30+ ) at 50% titration.

My volume of NaOH at 50% titration was calculated to be 5.00 mL and  the pH at 50% was 5.21.


How could I calculate H30+ at 50% titration?


Offline Borek

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Re: Potentiometric pH Titrations moles calculation
« Reply #5 on: April 23, 2009, 03:13:02 PM »
What is pH definition?
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