November 26, 2024, 11:56:40 PM
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Topic: prove that it is exothermic  (Read 4139 times)

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escapeartistq

  • Guest
prove that it is exothermic
« on: May 24, 2005, 06:21:48 PM »
Prove that 2C8H18(l) + 25O2(g) -> 16CO2(g) + 18H2O(g)

is exothermic, admiting that all gases behave like ideal gases.

I tried this:

?U = ?H + W
W = -RT?n
?n = (16+18) - 25 = 9  

so W < 0

How do you prove that AH < 0 as asked?

savoy7

  • Guest
Re:prove that it is exothermic
« Reply #1 on: May 24, 2005, 11:15:18 PM »
Use Hess's law to determine the heat of reaction.

http://energy.sdsu.edu/testcenter/testhome/Test/solve/basics/tables/tablesComb/formation.html
this site has some heats of formations that you can use to determine the heat of reaction.


escapeartistq

  • Guest
Re:prove that it is exothermic
« Reply #2 on: May 26, 2005, 06:28:58 AM »
Thanks, for your suggestion.  Now I see it was a stupid question because I thought there was a way to show that AH < 0 without recurring to Hess's law.

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