No.
You should write the expression for Ka. After you have an expression for Ka, start trying to relate any unknowns until you only have 1 unknown left.
How to find the relation you're looking for: Since acetic acid is a weak acid, write your equations as if it is initially undissociated and then partially dissociates into the conjugate base and H+. You don't know how much acetic acid was initially present but if you assume all of the H+ is from acetic acid then you do know how much of it dissociated. Your unknown, x, is the amount of acetic acid before it dissociated.