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Equilibrium Conc. tricky question
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Topic: Equilibrium Conc. tricky question (Read 3879 times)
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Equilibrium Conc. tricky question
«
on:
June 03, 2009, 01:06:31 PM »
I've had enuff >.< this dam question i cant seem to figure it out and ive tried every different thing i can think of soo far so if anyone else here can show me how to work it out itd b much appreciated :}
at 25 degrees C, Kc = 0.145 for the reaction in the solvent CCl
4
: 2BrCl
Br
2
+ Cl
2
IF the initial concentrations of each substance in a solution are 0.0400M - determine the equilibrium concentrations of each substance
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Borek
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Re: Equilibrium Conc. tricky question
«
Reply #1 on:
June 03, 2009, 02:22:46 PM »
Show you work so far.
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ChemBuddy
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Gargamel
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Re: Equilibrium Conc. tricky question
«
Reply #2 on:
June 03, 2009, 04:01:54 PM »
Try this
2BrCl
Br
2
+ Cl
2
Start 0,04M 0,04M 0,04M
End 0,04M-2x 0,04M+x 0,04M+x
Every time we use 2 mole of BrCl we get 1 mole of Br and 1 mole of Cl and vice versa.
Find x by using the equilibrum law, and I think you can figure out the rest.
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Re: Equilibrium Conc. tricky question
«
Reply #3 on:
June 03, 2009, 08:46:09 PM »
ok wat i did was work out that Qc was = 1.0 therefore Qc>Kc (1.0>0.145) sooo >.< i thought it meant i use up products therefore BrCl: 0.0400 + 2x ? and Cl2 = 0.04 - x ? no?
in any case i ended up with Kc = (0.4 -x)^2/(0.04 + 2x)^2 = 0.145 (im gonna take another stab at it now >.< )
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Gargamel
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Re: Equilibrium Conc. tricky question
«
Reply #4 on:
June 04, 2009, 07:00:35 AM »
Oh I'm so sorry if I confused you. You got it right! (forgot the stoichometric coefficient before BrCl so my Q was 0,04. But it is 1 as you say).
Just find x in your equation and insert in
[BrCl] = 0,04 + 2x
[Br
2
] = [Cl
2
] = 0,04 - x
Hope this help
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Equilibrium Conc. tricky question