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Offline Paulo Thompson

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Specific heat question
« on: June 21, 2009, 04:32:29 PM »
I'm studying for University entrance exam I have to take in November and have a question that is probably really simple. Here it is:


Q) An electric heater is submerged in 10° C water. 5 minutes later the water begins to boil at 100° C. If the heater is not turned off, all the water will evaporate and the heater will be damaged. How long after the water begins to boil will all of it evaporate?

Given: Specific heat of water - 1.0 cal/(g°C)
          Heat of vaporization - 540 cal/g

Offline Equilibria

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Re: Specific heat question
« Reply #1 on: June 25, 2009, 03:54:38 AM »
This type of question is pretty common in introductory engineering thermodynamics and chemical energetics courses. They can be quite challenging if you aren't used to deriving the information that has been omitted in the question.

The first step is to make a couple of assumptions:
- The heaters power output is constant
- No heat is lost to the environment (The process is 'Adiabatic')

Alright, now for the fun part. Using the first law of thermodynamics, the conservation of energy, we know that all of the energy coming from the heater is transferred to the water, and we know that it takes 1 calorie to raise 1g of water by 1°C. Ok, so what good is that? We are still missing the rate of energy coming from the heater and also the mass of the water.

Well, as it turns out, we can deal with this problem independent of the mass.

We can now say that the change in specific internal energy (Δu) of the water is proportional to the change in it's temperature (ΔT). This forms the 1st law expression:

Δu = specific heat x ΔT
Δu = 1cal/g°C x (100 - 50)°C
Δu = 50 cal/g

This means that the heater must be supplying 10 calories/g every minute. Now that we at a point where the water is boiling, all of the energy goes into releasing the water molecules from the liquid state instead of raising the temperature. Conveniently enough, they have provided you with a value that tells you how much energy this requires:
- Heat of vaporization - 540 cal/g

Using these two bits of information, we see that if we have 10 calories coming in each minute and we need 540 calories then the process is going to take 540/10 mins or 54 mins. Having said that, because of the lack of mass, we must remember that this is a specific value that means it will take 54mins/g of water.

Well, I hope that clears things up a bit for you. They may have intended something different but that's the answer that the question leads to.

Good luck on your entrance exam!



Offline typhoon2028

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Re: Specific heat question
« Reply #2 on: June 25, 2009, 08:22:30 AM »
The change in temperature is 90 C, so the boiling time = 30 min.

Offline Equilibria

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Re: Specific heat question
« Reply #3 on: June 28, 2009, 02:35:36 AM »
Haha My mistake! I should have paid more attention to the question myself, that's a fail right there. Sorry about that.

Offline Paulo Thompson

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Re: Specific heat question
« Reply #4 on: July 03, 2009, 12:15:41 PM »
Awesome. Thanks a lot. Do either of you guys have any tips for how to teach myself chemistry? I can memorize this formula (and I have already), but I'm not sure exactly why it's true.

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