Hmmm, for the first question, I think you should use the freezing point depression to calculate for the change in freezing point from water to the solution. First you need to find the freezing point constant (k) for ethanol and use the freezing point depression equation = i x k x molality, i in this case is the van 't Hoff i factor (basically separable parts from a chemical compound). For ethanol, I think it's just 1.
Your second question is very similar to the first, except this time they give you the change in freezing point of water. This time you would use the same equation and solve for molality and work your way from molality to find the mass and formula.
Hope this helps!