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Topic: Anyone knows how to produce ferrous sulfate from ferric oxide?  (Read 4018 times)

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Offline s4kho

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Currently I want to produce ferrous sulfate (FeSO4) from ferric oxide(Fe2O3)
anyone knows how to produce it?

If i react Fe2O3 with H2SO4, isn't the product Fe2(SO4)3 , which is Fe3+ and minor FeSO4
How to isolate them one to another?

maybe is it possible to reduce Fe2(SO4)3 to FeSO4 by adding iron metal itself?

Thank you for you reply
:)

Offline jcjlf

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Re: Anyone knows how to produce ferrous sulfate from ferric oxide?
« Reply #1 on: August 12, 2009, 11:09:42 AM »
You gave almost the right answer yourself:
Fe2O3 with dilute sulphuric acid gives a solution that contains Fe3+ ions and sulphate ions, no trace of FeSO4.
I would proceed as follows:
Add a reducing agent. Pure iron powder, in excess, is the most suitable, because no purification afterwards is necessary. You might also pass SO2 through the solution. But I think the Fe is preferable.
After the reaction has gone to completion, the yellow colour of the solution should have turned pale green. Let the solution evaporate to get the solid FeSO4.
Avoid the entrance of oxygen during the evaporating process (adding dry ice could be of help because it gives a protective carbon dioxide layer above the solution).
Equation without the sulphate spectator ions:
Fe(s) + 2 Fe3+(aq)  :rarrow: 3 Fe2+(aq)

Offline BluRay

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Re: Anyone knows how to produce ferrous sulfate from ferric oxide?
« Reply #2 on: August 13, 2009, 10:21:33 AM »
If you have Fe2O3 in the standard crystalline-red-powder form, you won't be able to dissolve it neither with dilute nor with concentrated H2SO4, and the same with HCl or HNO3 or H3PO4. If you want to dissolve it at cold, the best way I know is to use HF, otherwise melted K2S2O7.

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