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Topic: Formal charge question  (Read 2806 times)

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Offline maccha

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Formal charge question
« on: November 07, 2009, 01:46:26 PM »
Do complex ions form because of formal charges? For instance, in the hydroxide ion the oxygen has a negative formal charge.. is this what creates the overall negatively charged ion?

Offline aurophilic

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Re: Formal charge question
« Reply #1 on: November 07, 2009, 04:19:36 PM »
Yes, that sounds right.

Offline cth

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Re: Formal charge question
« Reply #2 on: November 08, 2009, 07:24:46 AM »
Partially yes. A negative charge on the ligand will help to bind to a positively charged metallic cation.

But some ligands are not actually charged, for example NH3, CO, PPh3, pyridine,... It is the lone electrons on the ligands that become shared with the metal cation when the complex form.

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