November 29, 2024, 07:30:18 PM
Forum Rules: Read This Before Posting


Topic: Carbocation rearrangement  (Read 3916 times)

0 Members and 1 Guest are viewing this topic.

Offline phymatter

  • Regular Member
  • ***
  • Posts: 18
  • Mole Snacks: +0/-0
Carbocation rearrangement
« on: November 12, 2009, 01:22:48 PM »
are there some restrictions on the structure for carbocation rearrangement?????

Offline Scatter

  • Regular Member
  • ***
  • Posts: 62
  • Mole Snacks: +3/-1
  • Gender: Male
Re: Carbocation rearrangement
« Reply #1 on: November 12, 2009, 07:30:18 PM »
Well, I don't know exactly what you mean when you say "restrictions" but there will never be a rearrangement that leaves the carbocation on a primary carbon.

From my understanding of it, rearrangements of a hydrogen or alkyl substituent happen to put the carbocation in a more stable position in the molecule, such as a teritiary or benzylic position.
« Last Edit: November 12, 2009, 07:41:46 PM by Scatter »

Offline srihari

  • Regular Member
  • ***
  • Posts: 47
  • Mole Snacks: +1/-0
  • Gender: Male
Re: Carbocation rearrangement
« Reply #2 on: November 13, 2009, 02:50:55 AM »
please make the question more specific .
life's game -play it

Sponsored Links