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Topic: New and have a Chemistry question  (Read 2930 times)

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Offline mazdarotary13

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New and have a Chemistry question
« on: December 01, 2009, 09:36:23 PM »
I was wondering if someone can help me with this problem. I would like someone to help explain the problem, not just give me the answer. much thanks, chemicalforums



Offline pear

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Re: New and have a Chemistry question
« Reply #1 on: December 01, 2009, 11:53:33 PM »
step 1: count the number of valence electrons
    H has 1 valence e- and each N has 5, so there are a total of 1 + (3x5) = 16 valence e-
step 2: arrange them in predicted order, the most electronegative atom in the center
   given by problem: H N N N
step 3: connect the atoms with a single bond
       H - N - N - N
step 4: place remaining electrons as lone pairs or as bonds around those atoms whose outer shell is incomplete
           (remember H only needs 2 [1s2])
       But Since I can't seem to find a way to show triple bonds, check out the possible answers and my reasoning.
       remember that the formal charge on each atom is it's valence electrons minus the number of e- assigned to it
       (each bond provides 1 e-; single bond = 1, double bond = 2, etc.)
            a) not a valid answer since no formal charge shown
            b) 16 e-; bonds good; H ok, N1 ok, N2 ok, and N3 ok.  works.
            c) 16 e-; bonds good; H ok, N1 ok, N2 ok, N3 ok.  works.
            d) 16 e-; bonds good; H ok, N1 ok, N2 ok, N3 ok.  works.
            e) bonds give a total of 22 e-; not possible.
            f) bonds give a total of 18 e-; not possible.

If you're starting from scratch and aren't given them to chose from, play with the e- arrangements once each atom is connected via a single bond and check that you haven't exceeded the number of valence e-'s.

Offline mazdarotary13

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Re: New and have a Chemistry question
« Reply #2 on: December 02, 2009, 07:00:25 PM »
Ohh wow. Thanks, a lot, pear. I found that extremely helpful.  ;D

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