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Topic: Reaction mechanism  (Read 3073 times)

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Offline jjkwest1

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Reaction mechanism
« on: February 09, 2010, 11:26:22 PM »
Consider the mechanism

ClO-(aq) +  :rarrow: HOCl(aq) + OH-     K,fast
I-(aq) + HOCl(aq) :rarrow: HOI(aq) +Cl-(aq)     k1,slow
HOI(aq) + OH-(aq) :rarrow: OI-(aq) +H2O(l)    k2,fast

What is the rate law?
a. k1K[CLO-][I-]
b. k1[I-][HOCl]
c. k1K[CLO-][I-][OH-]-1
d. k1K[CLO-][I-][OH-]
e. k1k2K[CLO-][I-]

i know that to determine the rate law you have to find the rate for the slow step thus i got
rate= k1[I-][HOCl]

however i know that HOCl can't be included in the rate law since it is an intermediate.
I'm kind of confused where to go from here, can anyone help me? thanks

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